Posting enhancer
Twhirl - With Twhirl you can have multiple Twitter accounts, connect to Friendfeed, post image to Twitpic and search using Tweetscan.
TweetCube - This service allows you to post/share zip, .rar, .pdf, .jpg, .png, .gif, .mp3 and .txt. files
Twit+ - With Twit+ you can tweet pictures, videos, and files publicly or privately among your friends on Twitter.
Twitter Feed - This tool allows you to send your blog atom or RSS feed to Twitter.
Twickie - Twickie is a service that fetches Twitter replies for you and gives you an easy way to view and export them.
GroupTweet - Allows you to post private message to a group of Twitter friends.
LinkBunch - With LinkBunch you can share more than one link in a tweet. This service puts together all the links and provides you one link that you can share on Twitter. This of course can be used with emails, IMs, SMS, etc.
For Reading
TopTweet - This site provides you updates from the top Twitter personalities.
TweetWire - Tweet Wire grabs the freshest links posted on Twitter and displays them Yahoo News page style.
Search
Summize - A Twitter search engine, one of the best in its kind. You can run a RSS feed on your query too and find tweets by language.
Quotably - Use Quotably to check out any Twitter user's conversations in a thread conversation style making it easier to follow. My favorite!
For Analytics
Sitevolume - This site allows you to see how many times a particular term has been used on Twitter, Digg, MySpace, YouTube and Flickr. You can type in various terms and see bar graphs comparing the terms.
TweetBeep - like Google Alerts, this service will send you an alert whenever your set keyword is typed on Twitter or when somebody links to your site.
Twitterlinkr - Shows you the popular links people are posting on Twitter.
@answerme - With this tool, you can track the questions you ask on Twitter.
Other Noteworthy Tools
TrackThis - This is a useful service to get updates on your consignment using Twitter. It supports FedEx, UPS, USPS and DHL tracking codes.
Twitzer - This Firefox add on lets you write more than 140 letters in your Twitter posts. The extra letters will be saved off-site and link to it will be placed on Twitter.
Twitscoop - This tool pulls out the words most used in Twitter every minute and displays on its site.
Who Should I follow - Find interesting people to follow on Twitter using this tool.